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Effects of sucrose crystallization and moisture migration on the structural changes of a coated intermediatemoisture food

Tiancheng LI, Peng ZHOU, Theodore P. LABUZA

《化学科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 346-350 doi: 10.1007/s11705-009-0256-8

摘要： The purpose of this study was to investigate whether moisture migration and sugar crystallization play an important role in the changes of IMF matrix structure. The migration of water was monitored with changes of water activity in different physical domains of samples during storage, while the crystallization of sucrose was determined with X-ray powder diffraction (XRD). The formation of both a hard inner-layer and agglomerated particles in the inner matrix was observed during storage. Our results suggested that both moisture loss and sucrose crystallization were mainly responsible for the formation of the crusty intermediate inner layer, and the agglomerated matrix particles were the result of sucrose crystallization.

关键词： inner-layer     agglomerated     IMF     moisture migration     crystallization    

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Theoretical study on the mechanism of sulfur migration to gas in the pyrolysis of benzothiophene

《化学科学与工程前沿（英文）》 2023年 第17卷 第3期   页码 334-346 doi: 10.1007/s11705-022-2209-4

摘要： The release and control of sulfur species in the pyrolysis of fossil fuels and solid wastes have attracted attention worldwide. Particularly, thiophene derivatives are important intermediates for the sulfur gas release from organic sulfur, but the underlying migration mechanisms remain unclear. Herein, the mechanism of sulfur migration during the release of sulfur-containing radicals in benzothiophene pyrolysis was explored through quantum chemistry modeling. The C1-to-C2 H-transfer has the lowest energy barrier of 269.9 kJ·mol–1 and the highest rate constant at low temperatures, while the elevated temperature is beneficial for C−S bond homolysis. 2-Ethynylbenzenethiol is the key intermediate for the formation of S and SH radicals with the overall energy barriers of 408.0 and 498.7 kJ·mol–1 in favorable pathways. The generation of CS radicals is relatively difficult because of the high energy barrier (551.8 kJ·mol–1). However, it can be significantly promoted by high temperatures, where the rate constant exceeds that for S radical generation above 930 °C. Consequently, the strong competitiveness of S and SH radicals results in abundant H2S during benzothiophene pyrolysis, and the high temperature is more beneficial for CS2 generation from CS radicals. This study lays a foundation for elucidating sulfur migration mechanisms and furthering the development of pyrolysis techniques.

关键词： benzothiophene     sulfur migration     pyrolysis     density functional theory    

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Wheel tracking methods to evaluate moisture sensitivity of hot-mix asphalt mixtures

Jie HAN,Harihar Shiwakoti

《结构与土木工程前沿（英文）》 2016年 第10卷 第1期   页码 30-43 doi: 10.1007/s11709-016-0318-1

摘要： Existing test methods to determine moisture sensitivity in hot-mix asphalt (HMA) mixtures are time consuming and inconsistent. This research focused on wheel tracking devices to evaluate moisture sensitivity. The Asphalt Pavement Analyzer (APA) and the Hamburg Wheel Tracking Device (HWTD) were used for this research. Compacted cylindrical samples were fabricated using a Superpave Gyratory compactor. This study selected two most commonly used mixtures, SM-12.5A with PG 64-22 binder in overlay projects and SM-19A mixtures with PG 64-22 binder for major modification projects at Kansas Department of Transportation. Test results show that APA tests could induce stripping in most samples without any anti-stripping agent, which could be identified visually. However, APA results did not indicate any stripping inflection point while the HWTD results showed stripping inflection points, which are important to identify stripping potential of mixtures. The APA results show that wet tests are severe at lower temperatures. The HWTD results show improvement in the performance using anti-stripping agents at later stage. The HWTD test is more effective as a rapid test method in case of determining moisture sensitivity. Laboratory results from this study should be verified and correlated with field performance.

关键词： hot-mix asphalt     moisture sensitivity     rutting     wheel tracking test    

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Solvates and polymorphs of clindamycin phosphate: Structural, thermal stability and moisture stability

Junbo Gong, Dejiang Zhang, Yuanyuan Ran, Keke Zhang, Shichao Du

《化学科学与工程前沿（英文）》 2017年 第11卷 第2期   页码 220-230 doi: 10.1007/s11705-017-1624-4

摘要： Clindamycin phosphate (CP), an antibacterial agent, has been reported to form several solid-state forms. The crystal structures of two CP solvates, a dimethyl sulfoxide (DMSO) solvate and a methanol/water solvate (solvate V), have been determined by single crystal X-ray diffraction. The properties and transformations of these forms were characterized by powder X-ray diffraction, Single-crystal X-ray diffraction, differential scanning calorimetry, thermo gravimetric analysis, hot-stage microscopy, and dynamic vapor sorption. Very different hydrogen bonding networks exist among the host-host and host-solvent molecules in the two crystal structures, resulting in different moisture stabilities. The thermal stabilities of the two solvates upon heating and desolvation were also studied. When the temperature was above the boiling point of methanol, solvate V converted to a polymorphic phase after a one step desolvation process, whereas the desolvation temperature of the DMSO solvate was below the boiling point of DMSO. At the relative humidity above 43%, the DMSO solvate transformed to a hydrate at 25 °C. In contrast, solvate V did not transform at any of the humidities studied.

关键词： clindamycin phosphate     solvate     crystal structure     thermal stability     moisture stability    

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Modeling temperature and moisture dependent emissions of carbon dioxide and methane from drying dairy

Enzhu HU, Pakorn SUTITARNNONTR, Markus TULLER, Scott B. JONES

《农业科学与工程前沿（英文）》 2018年 第5卷 第2期   页码 280-286 doi: 10.15302/J-FASE-2018215

摘要： Greenhouse gas emissions due to biological degradation processes of animal wastes are significant sources of air pollution from agricultural areas. The major environmental controls on these microbe-induced gas fluxes are temperature and moisture content. The objective of this study was to model the effects of temperature and moisture content on emissions of CO and CH during the ambient drying process of dairy manure under controlled conditions. Gas emissions were continuously recorded over 15 d with paired fully automated closed dynamic chambers coupled with a Fourier Transformed Infrared gas analyzer. Water content and temperature were measured and monitored with capacitance sensors. In addition, on days 0, 3, 6, 9, 12 and 15, pH, moisture content, dissolved organic carbon and total carbon (TC) were determined. An empirical model derived from the Arrhenius equation confirmed high dependency of carbon emissions on temperature and moisture content. Results indicate that for the investigated dairy manure, 6.83% of TC was lost in the form of CO and 0.047% of TC was emitted as CH . Neglecting the effect of temperature, the moisture contents associated with maximum gas emissions were estimated as 0.75 and 0.79 g·g for CO and CH , respectively.

关键词： carbon dioxide     dairy manure     methane     moisture     temperature    

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Regulatory factors of mesenchymal stem cell migration into injured tissues and their signal transduction

null

《医学前沿（英文）》 2011年 第5卷 第1期   页码 33-39 doi: 10.1007/s11684-011-0114-1

摘要：

Adult stem cells hold great promise for wound healing and tissue regeneration. Mesenchymal stem cells (MSCs), for example, have been shown to play a role in tissue repair. Research has shown that endogenous bone marrow MSCs or exogenously delivered MSCs migrate to the sites of injury and participate in the repair process. The precise mechanisms underlying migration of MSCs into the injured tissue are still not fully understood, although multiple signaling pathways and molecules were reported, including both chemoattractive factors and endogenous electric fields at wounds. This review will briefly summarize the regulatory facors and signaling transduction pathways involved in migration of MSCs. A better understanding of the molecular mechanisms involved in the migration of MSCs will help us to develop new stem cell-based therapeutic strategies in regenerative medicine.

关键词： mesenchymal stem cells     migration     molecular mechanisms     signaling pathway    

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The effect of texture and irrigation on the soil moisture vertical-temporal variability in an urban artificial

Xiaofeng ZHANG,Xu ZHANG,Guanghe LI

《环境科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 269-278 doi: 10.1007/s11783-014-0672-y

摘要： Soil moisture variability in natural landscapes has been widely studied; however, less attention has been paid to its variability in the urban landscapes with respect to the possible influence of texture stratification and irrigation management. Therefore, a case study was carried out in the Beijing Olympic Forest Park to continuously monitor the soil in three typical profiles from 26 April to 11 November 2010. The texture stratification significantly affected the vertical distribution of moisture in the non-irrigated profile where moisture was mostly below field capacity. In the profile where irrigation was sufficient to maintain moisture above field capacity, gravity flow led to increased moisture with depth and thus eliminated the influence of texture. In the non-irrigated sites, the upper layer (above 80 cm) exhibited long-term moisture persistence with the time scale approximating the average rainfall interval. However, a coarse-textured layer weakened the influence of rainfall, and a fine-textured layer weakened the influence of evapotranspiration, both of which resulted in random noise-like moisture series in the deeper layers. At the irrigated site, frequent irrigation neutralized the influence of evapotranspiration in the upper layer (above 60 cm) and overshadowed the influence of rainfall in the deeper layer. As a result, the moisture level in the upper layer also behaved as a random noise-like series; whereas due to deep transpiration, the moisture of the deep layer had a persistence time-scale longer than a month, consistent with characteristic time-scales found for deep transpiration.

关键词： moisture vertical distribution     moisture temporal variation     texture stratification     irrigation     meteorological forcing     urban landscape    

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Disabled homolog 2 is required for migration and invasion of prostate cancer cells

null

《医学前沿（英文）》 2015年 第9卷 第3期   页码 312-321 doi: 10.1007/s11684-015-0401-3

摘要：

Disabled homolog 2 (DAB2) is frequently deleted or epigenetically silenced in many human cancer cells. Therefore, DAB2 has always been regarded as a tumor suppressor gene. However, the role of DAB2 in tumor progression and metastasis remains unclear. In this study, DAB2 expression was upregulated along with human prostate cancer (PCa) progression. DAB2overexpression or knockdown effects in LNCaP and PC3 cell lines were verified to address the biological functions of DAB2 in PCa progression and metastasis. LNCaP and PC3 cell lines were generated from human PCa cells with low and high metastatic potentials, respectively. The results showed that DAB2 shRNA knockdown can inhibit the migratory and invasive abilities of PC3 cells, as well as the tumorigenicity, whereas DAB2 overexpression enhanced LNCaP cell migration and invasion. Further investigation showed that DAB2 regulated the cell migration associated genes in PC3 cells, and the differential DAB2 expression between LNCaP and PC3 cells was partly regulated by histone 4 acetylation. Therefore, DAB2 may play an important role in PCa progression and metastasis.

关键词： DAB2     prostate cancer     migration     invasion     acetylation    

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Influence of initial curing conditions and exposure environments on chloride migration in concrete using

Wen XUE, Weiliang JIN, Hiroshi YOKOTA,

《结构与土木工程前沿（英文）》 2010年 第4卷 第3期   页码 348-353 doi: 10.1007/s11709-010-0077-3

摘要： To investigate the influence of initial curing conditions and exposure environments on chloride ions’ migration in concrete, the specimens that were cured in different conditions and placed in several marine environments were studied. The amount of chloride ions passing through the specimen’s section was monitored in the accelerated chloride migration test. The effective chloride diffusion coefficients () were calculated from the steady-state on the basis of Nernst-Planck’s equation. The results indicated that the initial curing conditions and the wet-dry interval of external environments have coupling influence on effective diffusion coefficient of chloride ion significantly. reflected the density and pore connectivity of concrete. The co-effects of the initial curing condition and following exposure environment should be taken into account in durability design for concrete structure located in marine environment.

关键词： durability     effective diffusion coefficient     steady-state     migration test    

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Fighting for the poverty: a case study for human migration in the context of sustainable dryland farming

Yongqing MA, Jie CHEN, Shuqi DONG, Lun SHAN

《农业科学与工程前沿（英文）》 2014年 第1卷 第1期   页码 62-68 doi: 10.15302/J-FASE-2014027

摘要： The Southern Ningxia Hilly Area is one of the most impoverished areas of Ningxia Hui Autonomous Region (a province) of China due to an economy that mainly relies on agriculture, which is affected by droughts in two out of every three years. Government programs have attempted to develop an increased and sustainable level of scientifically based agricultural production while restoring the environment. However, since the population exceeds the capacity of the land to adequately support it, a program is underway to move 350000 people to more suitable locations. This paper outlines the past improvements to the Southern Ningxia Hilly Area and considers future development in the context of migration for ecological reasons.

关键词： agricultural production     animal husbandry     development strategy     ecological migration    

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Electromagnetic induction mapping at varied soil moisture reveals field-scale soil textural patterns

Hiruy ABDU, David A. ROBINSON, Janis BOETTINGER, Scott B. JONES

《农业科学与工程前沿（英文）》 2017年 第4卷 第2期   页码 135-145 doi: 10.15302/J-FASE-2017143

摘要： Knowledge of the spatial distribution of soil textural properties is important for determining soil moisture storage and soil hydraulic transport properties. Capturing field heterogeneity without exhaustive sampling and costly sample analysis is difficult. Our objective was to employ electromagnetic induction (EMI) mapping in low apparent electrical conductivity (EC ) soils at varying soil water contents to capture time invariant properties such as soil texture. Georeferenced EC measurements were taken using a ground conductivity meter on six different days where volumetric water content ( ) varied from 0.11 to 0.23. The 50 m × 50 m field included a subsurface gravelly patch in an otherwise homogeneous silt-loam alluvial soil. Ordinary block kriging predicted EC at unsampled areas to produce 1-m resolution maps. Temporal stability analysis was used to divide the field into three distinct EC regions. Subsequent ground-truthing confirmed the lowest conductivity region correlated with coarse textured soil parent materials associated with a former high-energy alluvial depositional area. Combining maps using temporal stability analysis gives the clearest image of the textural difference. These maps could be informative for modeling, experimental design, sensor placement and targeted zone management strategies in soil science, ecology, hydrology, and agricultural applications.

关键词： soil electrical conductivity     soil texture mapping     temporal stability analysis    

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Effects of miR-200c on the migration and invasion abilities of human prostate cancer Du145 cells and

null

《医学前沿（英文）》 2014年 第8卷 第4期   页码 456-463 doi: 10.1007/s11684-014-0353-z

摘要：

microRNAs (miRNAs) have played a key role in human tumorigenesis, tumor progression, and metastasis. On the one hand, miRNAs are aberrantly expressed in many types of human cancer; on the other hand, miRNAs can function as tumor suppressors or oncogenes that target many cancer-related genes. This study aimed to investigate the effects of miRNA-200c (miR-200c) on the biological behavior and mechanism of proliferation, migration, and invasion in the prostate cancer cell line Du145. In this study, Du145 cells were transfected with miR-200c mimics or negative control miR-NC by using an X-tremeGENE siRNA transfection reagent. The relative expression of miR-200c was measured by RT-PCR. The proliferation, migration, and invasion abilities of Du145 cells were detected by CCK8 assays, migration assays and invasion assays, respectively. The expressions of ZEB1, E-cadherin, and vimentin were observed by western blot. Results showed that DU145 cells exhibited a high expression of miR-200c compared with immortalized normal prostate epithelial cell RWPE-1. Du145 cells were then transfected with miR-200c mimics and displayed lower abilities of proliferation, migration, and invasion than those transfected with the negative control. The protein levels of ZEB1 and vimentin were expressed at a low extent in Du145 cells, which were transfected with miR-200c mimics; by contrast, E-cadherin was highly expressed. Hence, miR-200c could significantly inhibit the proliferation of the prostate cancer cell line Du145; likewise, miR-200c could inhibit migration and invasion by epithelial-mesenchymal transition.

关键词： miR-200c     proliferation     migration     invasion     prostate cancer     Du145 cell     ZEB1    

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A microarray study of altered gene expression during melanoblasts migration in normal pigmented White

Yulin LI,Deping HAN,Junying LI,Dawn KOLTES,Xuemei DENG

《农业科学与工程前沿（英文）》 2014年 第1卷 第4期   页码 299-306 doi: 10.15302/J-FASE-2014040

摘要： Melanoblasts originating from neural crest cells can migrate through the mesenchyme of the developed embryo and give rise to melanocytes. Unlike the melanocytes that are confined to the integument in other vertebrates, melanocytes in Silky Fowl can reach the ventral regions of the embryos owing to differences in gene expression in the process of melanoblasts migration. In this study, we used microarray profiling to identify differences in gene expression between White Leghorn and Silky Fowl. Differential expression of 2517 microarray probes ( <0.01, Fold Change>2) was observed in Silky Fowl compared to White Leghorn. After filtration by cluster analysis, functional annotation and pathway analysis, eight differentially expressed genes were identified to be closely related to the development of melanocytes. Moreover, differences in expression of immune genes were also detected between Silky Fowl and White Leghorn. The differentially expressed genes associated with melanocyte development were verified by q-PCR, and results were highly consistent with the microarray data. The genes with significantly altered expression involved in melanoblast migration and development suggested that different microenvironments resulted in the abnormal melanoblast migration in Silky Fowl, although there were no big differences in melanoblast development between these two breeds. The candidate genes discovered in this study are beneficial to understand the molecular mechanism of hyperpigmentation in Silky Fowl.

关键词： Silky Fowl     White Leghorn     melanoblast migration     gene expression    

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Migration and fate of polycyclic aromatic hydrocarbons in bioretention systems with different media:

《环境科学与工程前沿（英文）》 2023年 第18卷 第4期 doi: 10.1007/s11783-024-1802-9

摘要：

● Bioretention systems showed > 92% load reduction rates of PAHs.

关键词： Bioretention     Polycyclic aromatic hydrocarbons     HYDRUS-1D     Model simulation     Migration    

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Influence of the intensity and loading time of direct current electric field on the directional migration

null

《医学前沿（英文）》 2016年 第10卷 第3期   页码 286-296 doi: 10.1007/s11684-016-0456-9

摘要：

Exogenic electric fields can effectively accelerate bone healing and remodeling through the enhanced migration of bone marrow mesenchymal stem cells (BMSCs) toward the injured area. This study aimed to determine the following: (1) the direction of rat BMSC (rBMSC) migration upon exposure to a direct current electric field (DCEF), (2) the optimal DCEF intensity and duration, and (3) the possible regulatory role of SDF-1/CXCR4 axis in rBMSC migration as induced by DCEF. Results showed that rBMSCs migrated to the positive electrode of the DCEF, and that the DCEF of 200 mV/mm for 4 h was found to be optimal in enhancing rBMSC migration. This DCEF strength and duration also upregulated the expression of osteoblastic genes, including ALP and OCN, and upregulated the expression of ALP and Runx2 proteins. Moreover, when CXCR4 was inhibited, rBMSC migration due to DCEF was partially blocked. These findings indicated that DCEF can effectively induce rBMSC migration. A DCEF of 200 mV/mm for 4 h was recommended because of its ability to promote rBMSC migration, proliferation, and osteogenic differentiation. The SDF-1/CXCR4 signaling pathway may play an important role in regulating the DCEF-induced migration of rBMSCs.

关键词： DCEF     migration     osteogenesis differentiation     rBMSCs     SDF-1/CXCR-4    

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标题 作者 时间 类型 操作

Effects of sucrose crystallization and moisture migration on the structural changes of a coated intermediatemoisture food

Tiancheng LI, Peng ZHOU, Theodore P. LABUZA

期刊论文

Theoretical study on the mechanism of sulfur migration to gas in the pyrolysis of benzothiophene

期刊论文

Wheel tracking methods to evaluate moisture sensitivity of hot-mix asphalt mixtures

Jie HAN,Harihar Shiwakoti

期刊论文

Solvates and polymorphs of clindamycin phosphate: Structural, thermal stability and moisture stability

Junbo Gong, Dejiang Zhang, Yuanyuan Ran, Keke Zhang, Shichao Du

期刊论文

Modeling temperature and moisture dependent emissions of carbon dioxide and methane from drying dairy

Enzhu HU, Pakorn SUTITARNNONTR, Markus TULLER, Scott B. JONES

期刊论文

Regulatory factors of mesenchymal stem cell migration into injured tissues and their signal transduction

null

期刊论文

The effect of texture and irrigation on the soil moisture vertical-temporal variability in an urban artificial

Xiaofeng ZHANG,Xu ZHANG,Guanghe LI

期刊论文

Disabled homolog 2 is required for migration and invasion of prostate cancer cells

null

期刊论文

Influence of initial curing conditions and exposure environments on chloride migration in concrete using

Wen XUE, Weiliang JIN, Hiroshi YOKOTA,

期刊论文

Fighting for the poverty: a case study for human migration in the context of sustainable dryland farming

Yongqing MA, Jie CHEN, Shuqi DONG, Lun SHAN

期刊论文

Electromagnetic induction mapping at varied soil moisture reveals field-scale soil textural patterns

Hiruy ABDU, David A. ROBINSON, Janis BOETTINGER, Scott B. JONES

期刊论文

Effects of miR-200c on the migration and invasion abilities of human prostate cancer Du145 cells and

null

期刊论文

A microarray study of altered gene expression during melanoblasts migration in normal pigmented White

Yulin LI,Deping HAN,Junying LI,Dawn KOLTES,Xuemei DENG

期刊论文

Migration and fate of polycyclic aromatic hydrocarbons in bioretention systems with different media:

期刊论文

Influence of the intensity and loading time of direct current electric field on the directional migration

null

期刊论文